The finalists were:
- the four automatic qualifiers France, Germany, Spain and the United Kingdom;
- the top 10 countries from the 2005 final (other than the automatic qualifiers);
- the top 10 countries from the 2006 semi-final.
The final was held on 20 May 2006 at 21:00 (CET) and was won by Finland.
Countries in bold automatically qualified for the Eurovision Song Contest 2007 Final.
| Draw | Country | Language | Artist | Song | Place | Points |
|---|---|---|---|---|---|---|
| 01 | Switzerland | English | six4one | “If We All Give a Little” | 16 | 30 |
| 02 | Moldova | English, Spanish | Arsenium feat. Natalia Gordienko | “Loca” | 20 | 22 |
| 03 | Israel | English, Hebrew | Eddie Butler | “Together We Are One” | 23 | 4 |
| 04 | Latvia | English | Vocal Group Cosmos | “I Hear Your Heart” | 16 | 30 |
| 05 | Norway | Norwegian | Christine Guldbrandsen | “Alvedansen” | 14 | 36 |
| 06 | Spain | Spanish | Las Ketchup | “Un Blodymary” | 21 | 18 |
| 07 | Malta | English | Fabrizio Faniello | “I Do” | 24 | 1 |
| 08 | Germany | English | Texas Lightning | “No No Never” | 14[6] | 36 |
| 09 | Denmark | English | Sidsel Ben Semmane | “Twist of Love” | 18 | 26 |
| 10 | Russia | English | Dima Bilan | “Never Let You Go” | 2 | 248 |
| 11 | Macedonia | English, Macedonian | Elena Risteska | “Ninanajna” (Нинанајна) | 12 | 56 |
| 12 | Romania | English, Italian | Mihai Trăistariu | “Tornerò” | 4 | 172 |
| 13 | Bosnia and Herzegovina | Bosnian | Hari Mata Hari | “Lejla” | 3 | 229 |
| 14 | Lithuania | English, French[5] | LT United | “We Are the Winners” | 6 | 162 |
| 15 | United Kingdom | English | Daz Sampson | “Teenage Life” | 19 | 25 |
| 16 | Greece | English | Anna Vissi | “Everything” | 9 | 128 |
| 17 | Finland | English | Lordi | “Hard Rock Hallelujah” | 1 | 292 |
| 18 | Ukraine | English | Tina Karol | “Show Me Your Love” | 7 | 145 |
| 19 | France | French | Virginie Pouchain | “Il était temps” | 22 | 5 |
| 20 | Croatia | Croatian | Severina | “Moja štikla” | 12[6] | 56 |
| 21 | Ireland | English | Brian Kennedy | “Every Song Is a Cry for Love” | 10 | 93 |
| 22 | Sweden | English | Carola | “Invincible” | 5 | 170 |
| 23 | Turkey | English, Turkish | Sibel Tüzün | “Süper Star” | 11 | 91 |
| 24 | Armenia | English | André | “Without Your Love” | 8 | 129 |